硝酸盐/亚硝酸盐转化FeCoApplied Catalysis B: Environment and Energy

Interfacial Coupling Mediate Dual-Acceleration Strategy Enables Efficient Electrochemical Nitrate Reduction to Ammonia

研究概述

构建FeCo–CeO2催化剂，通过Fe位点活化硝酸根、Co位点生成活性氢，实现硝酸盐还原及含氮中间体氢化的协同加速。−0.5 V下产氨速率0.84 mmol·h⁻¹·cm⁻²，−0.3 V下法拉第效率97.35%。作为锌–硝酸盐电池正极时，最大功率密度7.34 mW/cm²。