RESEARCH / A0052
Engineering the Activity‐Selectivity Balance in Biomimetic MOF Nanozymes via Amino Acid‐Induced Pore Confinement
Read the original paper · 10.1002/adfm.77029 ↗
Source figures may contain other techniques and soft X-ray spectra. C, N and O measurements are outside our current hard-XAFS testing range.
FIGURE 1 (A) Scheme of the one-pot synthesis of AA-MIL-101(Fe), AA = Cys, His, Asp, and Pro. (B) SEM images of AA-MIL-101(Fe). (C) PXRD patterns and (D) FT-IR spectra of MIL-101(Fe) and AA-MIL-101(Fe). (E) XPS fully scanned spectrum of MIL-101(Fe) and AA-MIL-101(Fe). (F) Fe K- edge XANES spectra and (G) FT-EXAFS spectra of MIL-101 and AA-MIL-101(Fe), Fe foil, Fe2O3, and FeO. (H) N2 adsorption–desorption isotherms of MIL-101(Fe) and AA-MIL-101(Fe). (I) Micropores size distribution of MIL-101(Fe) and AA-MIL-101(Fe). (J) Average pore diameter of MIL-101(Fe) and AA-MIL-101(Fe).